The electrochemical reduction of carbon dioxide in methanol was investigated with cu and cu2osupported carbon black vulcan xc72 nanoparticle electrodes. Formation of hydrocarbons in the electrochemical reduction. In particular, the conversion of co2 into multicarbon products is of technological significance. Palladiumgold catalyst for the electrochemical reduction of. Electrochemical reduction of co2 in aqueous media is a strategy for sustainable production of fuels and commodity chemicals. Co2 is an attractive approach to store energy gener ated from intermittent renewable. Electrochemical reduction of carbon dioxide to ethanol. The selectivity and stability of hydrocarbon production is still a challenge. Electrochemical reduction of carbon dioxide wikipedia. Active and selective conversion of co2 to hydrocarbons is an important step toward a society based on renewable energy. Solar to chemical energy conversion could provide an alternative to mankinds unsustainable use of fossil fuels. Electrochemical reduction of carbon dioxide to hydrocarbons with. Electrochemical reduction of co2 to hydrocarbons to store.
Selective electrochemical conversion of co2 to c2 hydrocarbons. Supporting information as a service to our authors and readers, this journal provides supporting information supplied by the authors. The presence of the electrodeposits changes the catalytic behaviour of the substrates, since a hydrocarbons mixture with higher energetic density per volume is achieved when compared with the fuel resulting from co 2 reduction without electrodeposits. The use of electrochemical reduction of co 2 at a copper electrode to a hydrocarbon mixture looks like a promising technology, especially when applied to upgrading biogases. Electrochemical reduction an overview sciencedirect topics. Adsorbed co is reduced to hydrocarbons and alcohols at more negative potentials. Electrochemical reduction of carbon dioxide to ethanol 5 may 2020 credit. Therefore, numerous catalysts were investigated to increase the. However, electrocatalytic cc coupling in aqueous electrolytes is still an open challenge due to low selectivity. Electrochemical reduction of co2 over cu effects of. Understanding the roadmap for electrochemical reduction of co2 to multicarbon oxygenates and hydrocarbons on copperbased catalysts. Controllable hydrocarbon formation from the electrochemical reduction of co2 over cu nanowire arrays article pdf available in angewandte chemie international edition 5523 april 2016 with. Recently, the conversion of co 2 to useful fuels as a carbon source has attracted much attention due to its greenhouse effect and fossil shortage. Palladiumgold catalyst for the electrochemical reduction.
Selective electrocatalytic reduction of carbon dioxide to. However, direct electrochemical reduction of co 2 to hydrocarbons would be more ef. Formation of hydrocarbons in the electrochemical reduction of carbon dioxide at a copper electrode in aqueous solution august 1989 journal of the chemical society faraday transactions 1 858. Efficient conversion of co2 into hydrocarbons using renewable electricity would provide a renewable source of these chemicals and would also provide a high energy density means of storing renewable energy. Pdf electrochemical reduction of carbon dioxide at low.
We have studied the electrochemical reduction of co 2 to produce short chain hydrocarbons and alcohols using supported cu 2 o electrocatalysts. Electrochemical reduction of co2 into c1 and c2 hydrocarbons. Electrochemical reduction of co 2 to valueadded hydrocarbons is a promising solution to this issue, but poor selectivity and large overpotential of electrocatalysts slows its large scale application. Electrochemical carbon dioxide reduction in methanol at. Electrochemical reduction of co2 is a green chemistry way of recycling co2 back to reusable forms of carbon. Katy armstrong, in carbon dioxide utilisation, 2015. Electrochemical conversion of carbon dioxide to hydrocarbon fuels. Pdf understanding the mechanism of electrochemical. Better catalysts that exhibit high activity and especially. Electrochemical co2 reduction on cu electrode has attracted the attention of many researchers in the last decades, because of its potential to generate significant amounts of hydrocarbons at high reaction rates over sustained periods of time.
Electrochemical reduction of co2 to organic acids by a pd. Interestingly, copper has been identified as an ideal metal catalyst for an industrial scale electrochemical reduction of co2 to various valueadded chemicals relative to other metal catalysts reported so far. The copper is a promising catalyst for such a purpose. The potentially viable method of co2 electrolysis to hydrocarbons could utilize.
Electrochemical reduction of co2 over cu effects of surface. The resulting gas mixture, containing methane and hydrogen with small amounts of ethylene and carbon monoxide, has a similar energy. Revisiting electrochemical reduction of co2 on cu electrode. The porcu catalyst manifests high activity and selectivity for electrochemical co 2 reduction to hydrocarbons methane and ethylene. The electrochemical reduction of co2 with a cu electrode in liohmethanol based electrolyte was investigated. Solarpowered synthesis of hydrocarbons from carbon dioxide and. This reaction is of interest as a potential component of a carbon energy cycle i. The first section of this report introduces the technological aspects of the co 2 electrochemical cell, which in. Abstract electroreduction of carbon dioxide to c1 and c2 hydrocarbons has emerged as an efficient way to utilize carbon dioxide and maintain. Metal nanocatalysts have the potentials to selectively reduce co 2 to one carbon product co, formic acid, or a hydrocarbon. Here, we report a threestep synthesis using cuag bimetallic nanowire arrays as catalysts for electrochemical reduction of co2. Electrochemical reduction of co2 catalyzed by metal nanocatalysts. Jinli yu, haiyue liu, shuqin song, yi wang and panagiotis tsiakaras, electrochemical reduction of carbon dioxide at nanostructured sno 2 carbon aerogels.
Converting carbon dioxide into fuels and chemical feedstocks has attracted considerable attention 1,2. The electrochemical co2 reduction reaction co2rr catalyzed by metal nanostructures has been studied extensively in recent years. Cc0 public domain nus scientists have discovered a new mechanism for selective electrochemical reduction of carbon. Exploration of heterogeneous molecular catalysts combining the atomiclevel tunability of molecular structures and the practical handling advantages of heterogeneous catalysts represents an attractive approach to developing highperformance catalysts for important and challenging chemical reactions such as electrochemical carbon dioxide reduction which holds the promise for converting emissions back to fuels utilizing renewable energy. Co2 reduction catalysts and catalysis chem 462 kristina goldstein. Strategies in catalysts and electrolyzer design for. Cu metal embedded in oxidized matrix catalyst to promote co2. Electrochemical reduction of carbon dioxide co 2 rr to liquid fuels and valued chemicals is a meaningful approach to decreasing co 2 emissions and alleviating the energy crisis. Cu metal embedded in oxidized matrix catalyst to promote.
High hydrogen overvoltage electrodes with negligible co adsorption such as hg, cd, pb, tl, in and sn can reduce co 2 with a high current efficiency. Formation of hydrocarbons in the electrochemical reduction of. Here we report on the design and synthesis of a new noncoppercontaining catalyst able to reduce co2 to c1 to c5 hydrocarbons. The conductive support substrate is capable of incorporating a material to be reduced, such as co2 or co. The electrochemical reduction of carbon dioxide erc is the conversion of carbon dioxide to more reduced chemical species using electrical energy. Electrochemical reduction of carbon dioxide co2rr to liquid fuels and valued chemicals is a meaningful approach to decreasing co2 emissions and alleviating the energy crisis. Also, many multicarbon products are chemical feedstocks in high demand. Page 1 of 30 accepted manuscript 1 1 continuous electrochemical reduction of carbon dioxide into formate 2 using a tin cathode. May 22, 2017 electrochemical carbon dioxide co 2 reduction to hydrocarbons and alcohols presents one of the great challenges in chemistry. The electrochemical reduction of carbon dioxide to co is usually described as.
The synthesis of hydrocarbons from co 2 is a complex multistep reaction with adsorbed intermediates. Electroreduction of carbon dioxide to hydrocarbons using. Electrochemical reduction of co 2 is a green chemistry way of recycling co 2 back to reusable forms of carbon. Many attempts have been made to reduce the accumulation of atmosphere co 2, such as carbon capture and sequestration ccs, chemical usage, photochemical reduction, and electrochemical reduction. One promising approach is the electrochemical reduction of co2 into chemical products, in particular hydrocarbons and oxygenates which are formed by multielectron transfer reactions. The electrochemically prepared copperredox electrocathodes yield higher activity for the production of hydrocarbons at lower oxidation state. Electrochemical conversion of co 2 holds promise for utilization of co 2 as a carbon feedstock and for storage of intermittent renewable energy. Understanding trends in electrochemical carbon dioxide. Cu is the only catalyst which converts co2 to significant quantities of hydrocarbons and oxygenates. Electrochemical reduction of carbon dioxide on various metal. Copper is a unique electrocatalyst for co2 reduction, since it is one of the few catalysts able to produce methane, ethylene and ethane from co2 with decent faradaic efficiencies. By this simple synthesis method, cu nanowire array electrodes. The catalysts are prepared using cu 2 o nanoparticles formed by chemical reduction of aqueous cucl 2 mixed with polyethylene glycol surfactant, followed by addition of naoh and lascorbic acid sodium. Presently cu is the only metallic electrocatalyst known to reduce co 2 to appreciable amounts of hydrocarbons, but often a wide range of products such as co, hcoo, and h 2 are formed as well.
It is one possible step in the broad scheme of carbon capture and utilization. Electroreduction of carbon dioxide to c1 and c2 hydrocarbons has been emerged as an efficient way to utilize carbon dioxide and maintain the broken carbon. Electroreduction of carbon dioxide to c1 and c2 hydrocarbons has emerged as an efficient way to utilize carbon dioxide and maintain the broken carbon. Here we demonstrate that oxygenate products can be favored over hydrocarbons by pos. The first examples of electrochemical reduction of carbon dioxide are from the 19th century, when carbon dioxide was reduced to carbon monoxide using a zinc cathode. Electrochemical co2 reduction reaction co2rr offers a promising route for the production of chemicals and fuels using renewable electricity generated from wind and solar energy. Carbon dioxide electrochemical reduction dilute between feed carbon faradaic monoxide electrolyte ph a b s t r a c t electrochemicalconversion of co 2 touseful chemical intermediates maybe a promisingstrategy tohelp reduce co 2 emissions, while utilizing otherwise wasted excess renewable energy. Bell2,3,5 1institute of fuel cells, school of mechanical engineering, shanghai jiao tong university, shanghai, 200240 2joint center for artificial photosynthesis, lawrence berkeley national laboratory. There are known electrode catalysts that can facilitate the process. Electrochemical carbon dioxide co 2 reduction to hydrocarbons and alcohols presents one of the great challenges in chemistry.
Presently cu is the only metallic electrocatalyst known to reduce co2 to appreciable amounts of hydrocarbons, but often a wide range of products such as co, hcoo, and h2 are formed as well. Continuous electrochemical reduction of carbon dioxide. Electrosynthesis is actively studied as a science and also has industrial applications. Cu monolayer on auc and ptc for the electrochemical reduction of co2 to hydrocarbons article pdf available in ecs transactions 5049. Electrochemical reduction of carbon dioxide to hydrocarbons, driven by renewable power sources, is a fascinating and clean way to remedy greenhouse gas emission as a result of overdependence on fossil fuels and produce valueadded fine chemicals. In this work, the effect of cu nanowire morphology on the selective electrocatalytic reduction of co 2 is presented. The electrochemical conversion of carbon dioxide co2 into gaseous or liquid fuels has the potential to store renewable energies and reduce carbon emissions. Electrochemical carbon dioxide reduction in methanol at cu. This research has led to a better understanding of the reaction as it occurs on nanomaterial surfaces to achieve efficient conversion of co2 to specific carbon products.
The maximum current efficiency for hydrocarbons methane and ethylene was of 78%, at. The electrochemical reduction of carbon dioxide to formate. There are known electrode catalysts that can facilitate the. Controllable hydrocarbon formation from the electrochemical reduction of co2 over cu nanowire arrays. Pdf electroreduction of co2 at cu in aqueous inorganic electrolytes was studied by means of voltammetric, coulometric and chronopotentiometric. Brudvig, hailiang wang a department of chemistry, yale university, new haven, connecticut 06520, usa. Formation of hydrocarbons in the electrochemical reduction of carbon dioxide at a copper electrode in aqueous solution y. Formation of c2h4 and alcohols is favoured in kcl, k2so4. In particular, the conversion of co 2 into multicarbon products is of technological significance.
A metalfree electrocatalyst for carbon dioxide reduction. Thus far, efficient and selective electroreduction of co2 to deeply reduced products such as hydrocarbons remains a big challenge. Herein, cu or a cu2odeposited carbon black catalyst has been synthesized by the reduction method for a cu ion, and the dropcasting method was applied for the fabrication of a modified carbon black electrode. Also disclosed are electrochemical methods for generating hydrocarbon andor carbohydrate products from co2 or co using water as a source of hydrogen. Metal nanocatalysts have the potentials to selectively reduce co2 to one carbon product co, formic acid, or a hydrocarbon. An electrochemical carboxylation of a paraisobutyl benzyl chloride to ibuprofen is promoted under supercritical carbon dioxide. In this work, the effect of cu nanowire morphology on the selective electrocatalytic reduction of co2 is presented. An approach for synthesis of a hydrocarbon fuel from co 2 has been evaluated.
Us20180282885a1 nickel phosphide catalysts for direct. The effect of tin oxide content on the catalytic activity and formate selectivity, applied catalysis a. A novel approach for the conversion of co 2 by an electrochemical process has been achieved using copper electrodes modified with electrodeposits. Nanostructure control is essential for understanding co2 reduction reaction mechanism and for opti. In 20, mantra announced the completion of the first engineering design phase of an electro reduction of carbon dioxide erc pilot plant based at the lafarge cement plant in. Electrochemical co 2 reduction to fuels and chemicals using renewable electricity offers a green and efficient toolstrategy to mitigate global warming and energy supply problems. The selectivity and stability of hydrocarbon production is. Reducing carbon dioxide, an abundant carbon source, into valueadded fuels using a renewable energy input that is, arti. The synthesis of hydrocarbons via electroreduction of. Pdf formation of hydrocarbons in the electrochemical.
Palladiumgold catalyst for the electrochemical reduction of co2 to c1c5 hydrocarbons article pdf available in chemical communications 5267 june 2016 with 408 reads how we measure reads. Electrochemical reduction of carbon dioxide on various. Jan 19, 2020 our finding suggests a promising lead for the design of practical catalytic electrodes for the fuel synthesis with electrochemical co 2 reduction. Electrochemical reduction of carbon dioxide at low overpotential on a polyanilinecu2o nanocomposite based electrode. Electrochemical co 2 reduction to hydrocarbons on a heterogeneous molecular cu catalyst in aqueous solution zhe weng, a,b, a,b,cjianbing jiang, yueshen wu, a,b zishan wu, xiaoting guo, kelly l. Electrooxidation has potential for wastewater treatment as well.
The product distribution from co2 depends strongly upon the electrolytes employed. Electrochemical reduction of co2 catalyzed by metal. Our finding suggests a promising lead for the design of practical catalytic electrodes for the fuel synthesis with electrochemical co 2 reduction. Compared to ordinary redox reaction, electrosynthesis sometimes offers improved selectivity and yields. The electrochemical reduction of co2 has the potential to address many of the intertwined issues of energy security and climate change. Electrochemical co2 reduction to hydrocarbons on a heterogene.
Influence of dilute feed and ph on electrochemical reduction. Pdf formation of hydrocarbons in the electrochemical reduction of. Disclosed are cathodes comprising a conductive support substrate having a catalyst coating containing nickel phosphide nanoparticles. Electrochemical co2 reduction to hydrocarbons on a.
An overview of co2 electroreduction into hydrocarbons and. Electrochemical reduction is being used by the mantra venture group 17 to reduce co 2 to formic acid and formate salts. Here we report that nanometresize ndoped graphene quantum dots ngqds catalyse the electrochemical reduction of carbon dioxide into multicarbon hydrocarbons and. Microfluidic reactor for the electrochemical reduction of. Efficient solardriven electrochemical co2 reduction to.
1294 189 424 108 926 437 314 1465 620 1014 1458 1394 260 521 209 533 978 158 1277 27 301 1299 419 492 958 1064 74 505 1265 1204 230